Process and catalyst for production of rubbery polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526159, C08F 464, C08F 3606

Patent

active

039766306

ABSTRACT:
Rubbery polybutadiene containing at least 85 percent cis 1,4-addition can be made by polymerizing 1,3-butadiene with a catalyst formed from trialkylaluminum, for example, triethylaluminum, and titanium tetraiodide. The rubbery polybutadiene exhibits low hysteresis and is particularly useful in the manufacture of tires.

REFERENCES:
patent: 3178402 (1965-04-01), Smith et al.
Moyer et al., Journal Poly. Sci. Pt. A, vol. 3, pp. 217-229 (1965).

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