Cleaning and liquid contact with solids – Processes – For metallic – siliceous – or calcareous basework – including...
Reexamination Certificate
2005-03-22
2005-03-22
El-Arini, Zeinab (Department: 1746)
Cleaning and liquid contact with solids
Processes
For metallic, siliceous, or calcareous basework, including...
C134S002000, C134S019000, C134S026000, C134S030000, C134S033000, C134S031000, C134S025400, C134S902000, C134S102100, C134S102200, C134S108000, C134S111000, C134S199000
Reexamination Certificate
active
06869487
ABSTRACT:
A novel chemistry, system and application technique reduces contamination of semiconductor wafers and similar substrates and enhances and expedites processing. A stream of liquid chemical is applied to the workpiece surface. Ozone is delivered either into the liquid process stream or into the process environment. The ozone is preferably generated by a high capacity ozone generator. The chemical stream is provided in the form of a liquid or vapor. A boundary layer liquid or vapor forms on the workpiece surface. The thickness of the boundary layer is controlled. The chemical stream may include ammonium hydroxide for simultaneous particle and organic removal, another chemical to raise the pH of the solution, or other chemical additives designed to accomplish one or more specific cleaning steps.
REFERENCES:
patent: 4186032 (1980-01-01), Ham
patent: 4695327 (1987-09-01), Grebinski
patent: 4749440 (1988-06-01), Blackwood et al.
patent: 4778532 (1988-10-01), McConnell et al.
patent: 4817652 (1989-04-01), Liu
patent: 4899767 (1990-02-01), McConnell et al.
patent: 4917123 (1990-04-01), McConnell et al.
patent: 4974530 (1990-12-01), Lyon
patent: 5032218 (1991-07-01), Dobson
patent: 5055138 (1991-10-01), Slinn
patent: 5063609 (1991-11-01), Lorimer
patent: 5071485 (1991-12-01), Matthews et al.
patent: 5105556 (1992-04-01), Kurokawa et al.
patent: 5120370 (1992-06-01), Mori et al.
patent: 5181985 (1993-01-01), Lampert et al.
patent: 5232511 (1993-08-01), Bergman
patent: 5234540 (1993-08-01), Grant et al.
patent: 5235995 (1993-08-01), Bergman et al.
patent: 5244000 (1993-09-01), Stanford et al.
patent: 5246526 (1993-09-01), Yamaguchi et al.
patent: 5248380 (1993-09-01), Tanaka
patent: 5308745 (1994-05-01), Schwartzkopf
patent: 5326406 (1994-07-01), Kaneko et al.
patent: 5372651 (1994-12-01), Kodama
patent: 5378317 (1995-01-01), Kashiwase et al.
patent: 5415191 (1995-05-01), Mashimo et al.
patent: 5464480 (1995-11-01), Matthews
patent: 5503708 (1996-04-01), Koizumi et al.
patent: 5520744 (1996-05-01), Fujikawa et al.
patent: 5571367 (1996-11-01), Nakajima et al.
patent: 5632847 (1997-05-01), Ohno et al.
patent: 5647386 (1997-07-01), Kaiser
patent: 5658615 (1997-08-01), Hasebe et al.
patent: 5705089 (1998-01-01), Sugihara et al.
patent: 5714203 (1998-02-01), Schellenberger et al.
patent: 5749975 (1998-05-01), Li et al.
patent: 5776296 (1998-07-01), Matthews
patent: 5803982 (1998-09-01), Kosofsky et al.
patent: 5832177 (1998-11-01), Shinagawa et al.
patent: 5858107 (1999-01-01), Chao et al.
patent: 5896875 (1999-04-01), Yoneda
patent: 5911837 (1999-06-01), Matthews
patent: 5944907 (1999-08-01), Ohmi
patent: 5950643 (1999-09-01), Miyazaki et al.
patent: 5964952 (1999-10-01), Kunze-Concewitz
patent: 5964954 (1999-10-01), Matsukawa et al.
patent: 5971368 (1999-10-01), Nelson et al.
patent: 6146469 (2000-11-01), Toshima
patent: 6249933 (2001-06-01), Berfield
patent: 6267125 (2001-07-01), Bergman et al.
patent: 6273108 (2001-08-01), Bergman et al.
patent: 6299696 (2001-10-01), Kamikawa et al.
patent: 6551409 (2003-04-01), DeGendt et al.
patent: 0 344 764 (1989-12-01), None
patent: 04302145 (1992-10-01), None
patent: 0 548 596 (1993-06-01), None
patent: 0548 596 (1993-06-01), None
patent: 0 587 889 (1994-03-01), None
patent: 0 702 399 (1996-03-01), None
patent: 0 782 177 (1997-07-01), None
patent: 2 287 827 (1995-09-01), None
patent: 52-12063 (1977-04-01), None
patent: S61-004232 (1986-01-01), None
patent: 62-117330 (1987-05-01), None
patent: 63-110732 (1988-05-01), None
patent: 401042129 (1989-02-01), None
patent: H01-262627 (1989-10-01), None
patent: 03-072626 (1991-03-01), None
patent: H03-208900 (1991-09-01), None
patent: H04-125927 (1992-04-01), None
patent: H04-298038 (1992-10-01), None
patent: 4-302144 (1992-10-01), None
patent: 04-302145 (1992-10-01), None
patent: 04-370931 (1992-12-01), None
patent: 05-013398 (1993-01-01), None
patent: 05-109686 (1993-04-01), None
patent: 05-259139 (1993-10-01), None
patent: 05-283389 (1993-10-01), None
patent: 06-204130 (1994-07-01), None
patent: 07-159980 (1995-06-01), None
patent: 8-8222 (1996-01-01), None
patent: WO 9952654 (1999-10-01), None
Abstract of JP 3041729 published Feb. 22, 1991.
Abstract of JP 1008630, published Jan. 12, 1989.
Abstract of Japanese Appln. No. 63-16127 published Jul. 31, 1989.
Abstract of Japanese Appln. No. 52-100473 published Mar. 14, 1979.
Abstract of Japanese Appln. No. 1-192712 published Mar. 12, 1992.
Translation/Abstract of Japanese Appln. No. 1984-125760 published Jan. 10, 1986.
Heyns, M.M., et al. “New Wet Cleaning Strategies for Obtaining Highly Reliable Thin Oxides,” MRP Symposium Proceedings on Materials Research Society, Spring Meeting, San Francisco, CA Apr. 12-13, 1993, p. 35 (1993).
Adler, Marilyn Grace and Hall, George Richard, “The Kinetics and Mechanism of Hydroxide Ion Catalyzed Ozone Decomposition in Aqueous Solution”J.Am.Chem.Soc.,vol. 72, pp. 1884-1886, 1950.
Nelson, Steve, “Ozonated water for photoresist removal”Solid State Technology,pp. 107-112 (Jul. 1999).
Christenson, Kurt K., et al. “Deionized Water Helps Remove Wafer Stripping ‘Resist’-ance,” www.precisioncleaningweb.com—Precision Cleaning Web—Archives,pp. 10-20 (Apr. 1998).
Sehested, K., et al., “Decomposition of Ozone in Aqueous Acid Solutions (pH 0-4),”J. Phys. Chem.,pp. 1005-1009 (1992).
Krusell, W.C. et al., “Cleaning Technology for High Volume Production of Silicon Wafers,”ECS Proc. of the First Int'l. Symposium on Cleaning Technology I Semiconductor Device Mfg.,pp. 23-32 (Oct. 1989).
Vig, John R., “UV/Ozone Cleaning of Surfaces,”U.S. Army Elec. Tech. and Devices Lab.,pp. 1-26.
Vig, John R., “UV/Ozone Cleaning of Surfaces: A Review,”Surface Contamination: Genesis, Detection, and Control,pp. 235-253(1979).
Tong, Jeremy, et al., “Aqueous Ozone Cleaning of Silicon Wafers,”ECS Extended Abstracts,Phoenix, AZ, Abstract No. 506, pp. 753 (Oct. 13-17, 1991).
Zafonte, Leo, et al., “UV/Ozone Cleaning For Organics Removal on Silicon Wafers,”SPIE Optical Microlithography III: Technology for the Next Decade,vol. 470, pp. 164-175 (1984).
Baumgärtner, H., et al., “Ozone Cleaning of the SI-SIO2System,”Appl. Phys. A,vol. 43, pp. 223-226 (1987).
Isagawa, Tatsuhiko, et al., “Ultra Clean Surface Preparation Using Ozonized Ultrapure Water,”Extended Abstracts of the 1982 Int'l. Conf. on Solid State Devices and Materials,pp. 193-195 (1992).
Shimada, H., et al., “Residual-Surfactant-Free Photoresist Development Process,”J. Electrochem. Soc.,139(6):1721-1730 (Jun. 1992).
Tong, Jeremy K. et al., “Aqueous Ozone Cleaning of Silicon Wafers,”Proc. of 2ndInt'l. Symposium on Cleaning Tech In Semiconductor Device Mfg.,pp. 18-25 (Oct. 1992).
Tong, Jeremy K., et al., “Aqueous Ozone Cleaning of Silicon Wafers,”Res. Soc. Symp.,pp. 18-25 (1993).
Ohmi, T., et al., “Native Oxide Growth and Organic Impurity Removal on Si Surface with Ozone-Injected Ultrapure Water,”J. Electrochem. Soc.,140(3):804-810 (Mar. 1993).
Vig, John R., et al., “UV/Ozone Cleaning of Surfaces,”IEEE Transactions on Parts, Hybrids, and Packaging, vol. PHP-12(4):365-370 (Dec. 1976).
Vig, John R., “UV/ozone cleaning of surfaces,”U.S. Army Electronics Technology and Devices Laboratory ERADCOM,Ft. Monmouth, NJ, 07703-5302, pp. 1027-1034 (Sep./Oct. 1984).
Tabe, Michiharu, “UV ozone cleaning of silicon substrates in silicon molecular beam epitaxy,”Appl. Phys. Lett.,45(10):1073-1075 (Nov. 1984).
Zarrera, L.A., et al., “XPS and SIMS Study of Anhydrous HF and UV/Ozone-Modified Silicon (100) Surfaces,”J. Electrochem. Soc.,136(2):484-491 (Feb. 1989).
Gabriel, Calvin, et al., “Reduced Device Damage Using An Ozone Based Photoresist Removal Process,”SPIE Advances in Resist Technology and Processing VI,vol. 1086, pp. 598-604 (1989).
Suemitsu, Maki, et al., “Low Temperature Silicon Surface Cleaning b
El-Arini Zeinab
Perkins Coie LLP
Semitool Inc.
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