Process and apparatus for supplying metal ions to alloy electrop

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Treating process fluid by means other than agitation or...

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204237, 204DIG13, C25D 2118

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060568623

ABSTRACT:
Disclosed is a process for supplying nickel ions for a nickel alloy electroplating bath so as to replenish nickel ions consumed as electroplating progresses. The process uses an electrolysis cell, which is equipped with a rotatable cathode in the form of a drum or a disk having a surface of titanium or hard chromium plating; and an anode made of a titanium basket in which sulfur-containing metallic nickel is contained. Spent electroplating solution is electrolyzed in the electrolysis cell to dissolve nickel in the anode basket into the solution as ions and deposit a part of the dissolved nickel on the cathode, which is removed therefrom as the cathode rotates, while the rest of the dissolved nickel remains in the solution. The solution thus replenished with nickel ions is reused for the electroplating. The process may also be used to provide cobalt ions to replenish a spent cobalt alloy electroplating solution.

REFERENCES:
patent: 2541721 (1951-02-01), Roehl et al.
patent: 3474011 (1969-10-01), Guertin et al.

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