Process and apparatus for removal of H.sub.2 S from a process ga

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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423140, 423154, 423236, 423563, 423567A, C01B 1700

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active

051679400

ABSTRACT:
A method and apparatus for treating a catalytic polyvalent metal redox absorption solution, after absorption of H.sub.2 S from a gas, in a first hydrothermal treatment, to separate the polyvalent metal, for example as a polyvalent metal sulfide precipitate, and thereafter treating the redox solution in a higher temperature hydrothermal treatment to decompose thiosulfate salts and, if present, thiocyanide and other cyanide salts and metal-cyanide complexes to decompose the salts and complexes to molecules that can be treated in the H.sub.2 S-absorption process for recovery of sulfur and alkali values.

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"Treating hydrogen sulfide: An alternative to Claus" by L. C. Hardison; Chemical Engineering, Jan. 21, 1985 by McGraw-Hill Inc.
"Unit Operations of Chemical Engineering" by McCabe and Smith; McGraw-Hill Inc. (1956) p. 580.
"Grant and Hackh's Chemical Dictionary" 5th ed. by Roges and Claire Grant, p. 37.

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