Process and apparatus for generating high density hydrogen in a

Details Process and apparatus for generating high density hydrogen in a Process and apparatus for generating high density hydrogen in a

1989-03-31

1991-01-22

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

Electrostatic field or electrical discharge

204242, 204292, C25B 102

Patent

active

049868870

ABSTRACT:
A process is described wherein hydrogen and its isotopes are dissolved in palladium metal in high density by utilizing electrochemical methods in an electrolytic cell. The cell has an inert anode and a palladium containing cathode, both being immersed in an electrolyte which contains a lithium salt dissolved in an aprotic solvent, and a small amount of water. The dissolved hydrogen to palladium ratio in the palladium bearing cathode, which may be achieved by this process, is in excess of 0.95.

REFERENCES:
patent: 3433722 (1969-03-01), Weininger et al.
patent: 3476607 (1969-11-01), Berger
patent: 3923542 (1975-12-01), von Benda et al.
Dandapani et al., "Electrolytic Separation Factors on Palladium", Journal of Electroanalytical Chemistry, vol. 39, 1972, pp. 315-332.
Farkas, "On the Electrolytic Separation of the Hydrogen Isotopes on a Palladium Cathode", Trans. Faraday Soc., Apr. 1937; pp. 552-558.

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