Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2001-03-16
2004-03-16
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C502S160000
Reexamination Certificate
active
06706810
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to primers/primer surfacers, that will be applied to any substrate that will be painted and more particularly to metal, fiberglass, SMC, plastic or wood that will be painted, and it particularly relates to a primer/primer surfacer to be used in the field of automotive, marine, agricultural and industrial equipment.
There are many primer/primer surfacers on the market which used as primer to prepare the surface to be painted. Traditional primers are being gradually pushed out of the market due to changing environmental regulations. As a result, trying to create a new, volatile organic compound (VOC) compliant, high performance and user friendly primer has become important for manufacturers, such as manufacturers of automotive, marine, agricultural and industrial equipment.
Traditional urethane technology has thus far not been successfully used because of problems integrating high solids, and exempt (VOC compliant) solvent into urethane primers. Shrinkage and other poor performance characteristics have not been overcome. The epoxy system also suffers from poor performance characteristics, including long dry time and poor sanding. Acrylics (air-dry) systems have inherent VOC and shrinkage problem, and poor integrity.
The traditional polyester system brought solid performance at VOC complaint levels, with most of the benefits of epoxy and urethanes obtained without the liabilities of shrink, slow dry/cure, and poor sanding. The problem with traditional polyester primer technology is the catalyzation amount. The catalyzation amount was very subjective and prone to error. In addition, the ketone peroxide, such as methyl ethyl ketone-peroxide (MEKP), traditionally used as the catalyst has oxidative and corrosive properties that present some risks from a health and safety point of view. Also, the concentrated peroxide is susceptible to premature decomposition, gassing, and loss of reactive properties (active oxygen) if stored improperly.
There have been attempts to overcome these deficiencies by using vinyl polyester (VPE). Vinyl ester, polyester, and VPE are cured with MEKP at 2% by weight. One problem is to find a way to stabilize the MEKP so that it can be mixed with the primer in a ratio other than 2%.
Thus, there is a need in the art for a new polyester system that will lower the VOC, maintain the excellent performance of a primer, and improve the mix ratio.
SUMMARY OF THE INVENTION
This invention fulfills that need by providing a primer composition that will lower the VOC, maintain excellent performance of the primer, and improve the mix ratio. This is accomplished by mixing methyl ethyl ketone peroxide (MEKP) with a solvent which is either ethyl acetate, methyl acetate, t-butyl acetate, or mixtures thereof. The solvent keeps the MEKP from decomposing while keeping the potency to cure the primer in the same required time.
In accordance with one embodiment of the present invention, a primer composition is provided comprising an ester, methyl ethyl ketone peroxide, and a sufficient amount of solvent to stabilize the methyl ethyl ketone peroxide. The ester in primer composition is selected from the groups consisting of polyester, vinyl ester, vinyl polyester, and mixtures thereof. The solvent in the primer composition is mixed with the methyl ethyl ketone peroxide.
In accordance with another embodiment of the present invention, a method of stabilizing a primer composition is provided comprising the steps of mixing methyl ethyl ketone peroxide with a sufficient amount of solvent to stabilize the methyl ethyl ketone peroxide, then adding the mixture to a primer composition. The solvent used in the method of stabilizing a methyl ethyl ketone peroxide catalyst is selected from the group consisting of ethyl acetate, methyl acetate, t-butyl acetate, and mixtures thereof.
In accordance with another embodiment of the present invention, a stabilized methyl ethyl ketone peroxide catalyst is provided comprising methyl ethyl ketone peroxide and a sufficient amount of a solvent to stabilize the methyl ethyl ketone peroxide. The solvent in the stabilized methyl ethyl ketone peroxide catalyst is selected from the group consisting of ethyl acetate, methyl acetate, t-butyl acetate, and mixtures thereof.
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patent: 5236975 (1993-08-01), Sekine
patent: 5843221 (1998-12-01), Parish
patent: 5965672 (1999-10-01), Agari et al.
patent: 5993116 (1999-11-01), Paxton et al.
patent: 6051242 (2000-04-01), Patel et al.
Marzouk Mohsen S.
Reynolds Jeffrey Andrew
Cain Edward J.
Dinsmore & Shohl LLP
Illinois Tool Works Inc.
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