Stock material or miscellaneous articles – Composite – Of silicon containing
Reexamination Certificate
2001-09-10
2003-11-25
Dawson, Robert (Department: 1712)
Stock material or miscellaneous articles
Composite
Of silicon containing
C106S287160, C106S287110, C428S447000, C524S838000, C528S023000, C528S034000, C528S038000
Reexamination Certificate
active
06652977
ABSTRACT:
FIELD OF THE INVENTION
The present invention is directed to a primer composition. More particularly, the invention is directed to a primer composition comprising a coupling-agent and a cross-linking agent. The primer composition adheres well to metal surfaces and may be used to treat metal surfaces in order to enhance paint adhesion and corrosion resistance properties of the surfaces. Such enhancement of properties unexpectedly results without employing, among other things, environmentally unfriendly agents in the primer composition.
BACKGROUND OF THE INVENTION
It is well known that metal parts typically require cleaning before they are subjected to a final coating stage, such as a painting stage. This is true because many metal parts (e.g., auto parts, appliance parts, furniture parts) are typically made and/or molded in environments that generate metal shavings and/or sludge. Moreover, such metal parts have surfaces that are often contaminated with grease (or other lubricants) as a result of manufacturing processes.
Present methods for cleaning soiled metal parts typically use an alkaline detergent composition to initially wash the soiled metal part. Subsequent to the initial wash, the metal part is rinsed with water and then subjected to a phosphate coating process. Conventional phosphate coating processes generally employ a phosphate coating technique that utilizes zinc, iron or manganese phosphate in an acidic bath or spray. After coating the metal part with phosphate, a rinse occurs to remove any active chemicals that remain on the surface of the metal. The resulting treated metal part is then given a final chemical treatment, like a chromic acid rinse. The chemical treatment is generally desired to ensure that the metal part is made corrosion resistant and that no phosphating acid and hard water salts remain on the metal parts before the required drying, and painting steps.
The conventional method outlined above (and generally accepted by the ASM Committee on Phosphate Coating) uses primer compositions that require the presence of environmentally unfriendly agents. The conventional method also requires many processing steps, including a drying step and a final rinse step after the primer composition is applied. It is of increasing interests to develop a primer composition that may be easily applied, does not employ environmentally unfriendly agents and does not require a rinsing step after application. This invention, therefore, is directed to an environmentally friendly primer composition that does not contain or require the use of metal phosphates and/or any transition metal acids, like chromic acid. Moreover, the environmentally friendly primer composition of the present invention is capable of being used where dry-in-place primer applications are desired.
Additional Information
Efforts have been disclosed for treating metal surfaces. In U.S. Pat. No. 6,179,934, an aqueous zinc phosphate conversion coating having a hydroxylamine source is described.
Still other efforts have been disclosed for treating metal surfaces. In U.S. Pat. No. 6,197,126, a nickel-free, copper-containing phosphate composition is disclosed wherein the composition may be used to treat metal surfaces to improve lacquer adhesion.
Even further in U.S. Pat. No. 6,171,409, a method for treating metal surfaces with a phosphating or pickling solution is described whereby the process includes at least one vigorous and thorough mixing step.
None of the references mentioned above describes a primer composition having a coupling-agent and a cross-linking agent as disclosed in the present invention. Additionally, metal, as used herein, is defined to mean a substance comprising a transition metal or aluminum, or a substance capable of being a conductor of electricity, or any combination thereof. Good adhesion properties, as used herein, are defined to mean having a creepage value of 2.75 millimeters or less after 508 hours and/or of 4.25 millimeters or less after 1008 hours. Dry-in-place, as used herein, is defined to mean ready to be painted without having to be rinsed.
SUMMARY OF THE INVENTION
In a first aspect, the present invention is directed to a primer composition comprising a cross-linking agent and a coupling-agent wherein the cross-linking agent comprises silicon and the coupling-agent comprises silicon.
In a second aspect, the present invention is directed to a method which uses the primer composition of the first aspect, including a method for reducing corrosion (e.g., rust) on metal surfaces.
In a third aspect, the present invention is directed to a substrate having been subjected to the primer composition described above.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
There is no limitation with respect to the cross-linking agent that may be used in this invention other than that the cross-linking agent is one which may be used in a primer composition. In a preferred embodiment, however, the cross-linking agent comprises at least three (3) sites of cross-linking reactivity, and has the general formula:
wherein X is a trivalent group, each Y is independently a divalent group (i.e., divalent bridging radical), each Q is independently or or a combinations of —R and —OR and each R is independently a C
1-10
alkyl group or an aryl group.
In a more preferred embodiment, X has the formula selected from:
wherein W is C, N or P, R
1
is a H, C
1-10
alkyl or aryl, with the proviso that i is 1 when W is C, and i is 0 when W is not C, and each Y is independently
or
with n being an integer from about 1 to about 10.
In a most preferred embodiment, X is represented by Formula III, each Y is
and Q is OR and R is a methoxy group.
Such a most preferred cross-linking agent is made available by OSi Specialties and sold under the name Silquest® Y-11597. Regarding the coupling-agent which may be used in this invention, such a coupling-agent is limited only to the extent that it may be used in a primer composition. The coupling-agent may be selected from compounds like gamma-aminopropyltriethoxysilane (Silquest®A-1101 silane, and Silquest®A-I 102 silane), aminoalkyl silicone solution (Silquest®A-1106 silane), modified aminoorganosilane (Silquest®A-1108 silane and Silquest®A-1126 silane), gamma-aminopropyltrimethoxysilane (Silquest®A-1110 silane), N-beta (aminoethyl)-gamma-aminopropyltrimethoxysilane (Silquest®A-1120 and Dow Corning®Z-6020 silane), modified aminosilane (Sllquest®A-1128 silane), triaminofunction silane (Silquest®A-1130 silane) N-phenyl-gamma-aminopropyltrimethoxysilane (Silguest®Y-9669 silane), organomodified polydimethylsiloxane (Silquest®Y-11343 silane), polyazamide silane (Silquest®A-1187 silane), or N-beta-(aminoethyl)-gamma-aminopropylmethyldimethoxysilane (Silquest®a-2120 silane), whereby the compounds are made available by Osi Specialties. These are water soluble silanes.
In a preferred embodiment, however, the coupling-agent of this invention comprises at least one (1) site of coupling reactivity, and has the general formula:
wherein Z is a monovalent or divalent portion of the coupling-agent, Y and Q are as previously defined and q is 1 when Z is monovalent and 2 when Z is divalent.
In a more preferred embodiment, Z, when monovalent, is
and, when divalent,
where R
1
is as previously defined and each Y is independently a
with n being as previously defined.
In a most preferred embodiment, Z, when monovalent, is —NH
2
and, when divalent
and Y is
and R is —OCH
2
CH
3
.
Such most preferred coupling-agents are made available by OSi Specialties. When q is 1, the coupling-agent is referred to as gamma-aminopropyltriethoxysilane, and when q is 2, the coupling-agent is referred to as bis-(gamma-triethoxysilylpropyl) amine, sold under the names Silquest A-1100 and Silquest A-1170, respectively.
When preparing the primer composition of the present invention, it is generally preferred to employ from about 0.0001 to about 30.0%, and preferably, from about 0.0005 to about 15%, and most preferably, from about 0.0008 to about 1.0% by weight cross-linking agent, based on total weight of the pri
Dawson Robert
Johnson Diversey, Inc.
Wood Herron & Evans L.L.P.
Zimmer Marc S
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