Prevention of overpressurization of lithium-thionyl chloride bat

Chemistry: electrical current producing apparatus – product – and – Sealed cell having gas prevention or elimation means

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429101, 429196, 429199, 429218, H01M 1034, H01M 614, H01M 604

Patent

active

044904460

ABSTRACT:
A method of preventing overpressurization of a lithium-thionyl chloride battery cell by formation of excessive SO.sub.2 during high rate discharge. The method comprises the step of providing PCl.sub.5 in the cathode. Alternatively, the PCl.sub.5 may be provided in the electrolyte or in both the cathode and electrolyte as desired. The PCl.sub.5 may be incorporated in the cathode by introduction thereof into the porous carbon structure of a preformed carbon element. Alternatively, the PCl.sub.5 may be dry mixed with the carbon and the mixture formed into the desired cathode element.

REFERENCES:
patent: 4262065 (1981-04-01), Giattino
patent: 4293622 (1981-10-01), Marancic et al.
patent: 4296185 (1981-10-01), Catanzarite
patent: 4360572 (1982-11-01), Chua et al.

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