Pretreatment and regeneration of oxides of manganese

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

Reexamination Certificate

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Reexamination Certificate

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07041270

ABSTRACT:
The invention relates to systems and processes for treating particulate oxides of manganese useful as oxidizing sorbents for capturing or removing target pollutants from industrial gas streams, including, but not limited to, nitrogen oxides (NOx), sulfur oxide (SOx), mercury (Hg), hydrogen sulfide (H2S), other totally reduced sulfides (TRS), and oxides of carbon (CO and CO2) gases. Oxides of manganese are washed an aqueous oxidizing solution, which may be adjusted as necessary to maintain the oxidizing solution a desired range of pH (acidity) and Eh (oxidizing potential) within the MnO2stability area for aqueous solutions. The resulting treated oxides of manganese are equally or more efficient as sorbents as the oxides of manganese processed with the invention.

REFERENCES:
patent: 1178927 (1916-11-01), Kaplan
patent: 1275666 (1918-08-01), Ellis et al.
patent: 1293461 (1919-02-01), Kaplan
patent: 1330738 (1920-02-01), Ellis et al.
patent: 1851312 (1932-03-01), Huff
patent: 2123250 (1938-07-01), Muller et al.
patent: 2486530 (1949-11-01), Jenness
patent: 2608466 (1952-08-01), Fox
patent: 2956860 (1960-10-01), Welsh
patent: 2984545 (1961-05-01), Tarbutton et al.
patent: 3011867 (1961-05-01), Welsh
patent: 3150923 (1964-09-01), Bienstock et al.
patent: 3226192 (1965-12-01), Atsukawa et al.
patent: 3251649 (1966-05-01), Atsukawa et al.
patent: 3330096 (1967-07-01), Zimmerley
patent: 3427128 (1969-02-01), Schmier
patent: 3723598 (1973-03-01), Spedden
patent: 3780158 (1973-12-01), Welsh
patent: 3798310 (1974-03-01), Atsukawa et al.
patent: 3898320 (1975-08-01), Atsukawa et al.
patent: 3933128 (1976-01-01), Cramer
patent: 3951765 (1976-04-01), Everett
patent: 3956189 (1976-05-01), Warshaw et al.
patent: 3957949 (1976-05-01), Senjo et al.
patent: 3981971 (1976-09-01), Saito et al.
patent: 4006217 (1977-02-01), Faber et al.
patent: 4008169 (1977-02-01), McGauley
patent: 4011298 (1977-03-01), Fukui et al.
patent: 4012487 (1977-03-01), Merkl
patent: 4014982 (1977-03-01), Paull et al.
patent: 4017586 (1977-04-01), Reeves
patent: 4029752 (1977-06-01), Cahn
patent: 4033113 (1977-07-01), Cramer
patent: 4070441 (1978-01-01), Pessel
patent: 4081509 (1978-03-01), Hishinuma et al.
patent: 4087372 (1978-05-01), Saitoh et al.
patent: 4091075 (1978-05-01), Pessel
patent: 4102982 (1978-07-01), Weir
patent: 4108969 (1978-08-01), Merkl
patent: 4112053 (1978-09-01), Sanada et al.
patent: 4123499 (1978-10-01), Welsh et al.
patent: 4123507 (1978-10-01), Hass
patent: 4153429 (1979-05-01), Matthews et al.
patent: 4162207 (1979-07-01), Boyer et al.
patent: 4164545 (1979-08-01), Scott
patent: 4233188 (1980-11-01), Gandhi et al.
patent: 4250149 (1981-02-01), Welsh
patent: 4276268 (1981-06-01), Welsh
patent: 4277360 (1981-07-01), Mellors et al.
patent: 4309386 (1982-01-01), Pirsh
patent: 4309392 (1982-01-01), Shaw et al.
patent: 4310494 (1982-01-01), Welsh
patent: 4369108 (1983-01-01), Bertolacini et al.
patent: 4369130 (1983-01-01), Bertolacini et al.
patent: 4369167 (1983-01-01), Weir, Jr.
patent: 4376103 (1983-03-01), Bertolacini et al.
patent: 4381991 (1983-05-01), Bertolacini et al.
patent: 4400362 (1983-08-01), Lerner
patent: 4402931 (1983-09-01), Tanabe et al.
patent: 4411878 (1983-10-01), Welsh
patent: 4423019 (1983-12-01), Bertolacini et al.
patent: 4448760 (1984-05-01), Welsh
patent: 4450148 (1984-05-01), Welsh
patent: 4476104 (1984-10-01), Mellors
patent: 4479877 (1984-10-01), Guter
patent: 4497902 (1985-02-01), Bertolacini et al.
patent: 4500281 (1985-02-01), Beardmore
patent: 4542116 (1985-09-01), Bertolacini et al.
patent: 4550098 (1985-10-01), Gens
patent: 4551254 (1985-11-01), Imada et al.
patent: 4552734 (1985-11-01), Iannicelli et al.
patent: 4552735 (1985-11-01), Iannicelli et al.
patent: 4581210 (1986-04-01), Teller
patent: 4581219 (1986-04-01), Imada et al.
patent: 4713225 (1987-12-01), Iannicelli
patent: 4755499 (1988-07-01), Neal et al.
patent: 4798711 (1989-01-01), Neal et al.
patent: 4836993 (1989-06-01), Bertolacini et al.
patent: 4843980 (1989-07-01), Markham et al.
patent: 4871522 (1989-10-01), Doyle
patent: 4872989 (1989-10-01), Pirotta
patent: 4883647 (1989-11-01), Kainer et al.
patent: 4908194 (1990-03-01), Hooper
patent: 4915922 (1990-04-01), Filss
patent: 4921689 (1990-05-01), Walker et al.
patent: 4923688 (1990-05-01), Iannicelli
patent: 4925633 (1990-05-01), Doyle
patent: 4940569 (1990-07-01), Neal et al.
patent: 4944878 (1990-07-01), Lockridge et al.
patent: 4954324 (1990-09-01), Hooper
patent: 5000930 (1991-03-01), Boguslawski
patent: 5009872 (1991-04-01), Chuang et al.
patent: 5023063 (1991-06-01), Stiles
patent: 5059406 (1991-10-01), Sheth et al.
patent: 5112796 (1992-05-01), Iannicelli
patent: 5176888 (1993-01-01), Stiles
patent: 5192515 (1993-03-01), Gardner-Chavis et al.
patent: 5199263 (1993-04-01), Green et al.
patent: 5200160 (1993-04-01), Benson et al.
patent: 5246554 (1993-09-01), Cha
patent: 5277890 (1994-01-01), Wang et al.
patent: 5348726 (1994-09-01), Wang et al.
patent: 5366710 (1994-11-01), Chou et al.
patent: 5384301 (1995-01-01), Flytzani-Stephanopoulos et al.
patent: 5391365 (1995-02-01), Wang et al.
patent: 5439658 (1995-08-01), Johnson et al.
patent: 5456892 (1995-10-01), Yang et al.
patent: 5505766 (1996-04-01), Chang
patent: 5607496 (1997-03-01), Brooks
patent: 5658544 (1997-08-01), Goodes
patent: 5672323 (1997-09-01), Bhat et al.
patent: 5700439 (1997-12-01), Goyette et al.
patent: 5780000 (1998-07-01), Strickland
patent: 5798088 (1998-08-01), Dorchak et al.
patent: 5853684 (1998-12-01), Fang et al.
patent: 5888926 (1999-03-01), Biswas et al.
patent: 6010666 (2000-01-01), Kurokawa et al.
patent: 6039783 (2000-03-01), Lueck et al.
patent: 6066590 (2000-05-01), Horii et al.
patent: 6132692 (2000-10-01), Alix et al.
patent: 6162530 (2000-12-01), Xiao et al.
patent: 6214304 (2001-04-01), Rosenthal et al.
patent: 6605263 (2003-08-01), Alix et al.
patent: 6610263 (2003-08-01), Pahlman et al.
patent: 2003/0108466 (2003-06-01), Alix et al.
patent: 2003/0108469 (2003-06-01), Alix et al.
patent: 2003/0108472 (2003-06-01), Duncan et al.
patent: 33 12 890 (1984-10-01), None
patent: OS 3731889 (1989-04-01), None
patent: 40 12 982 A11 (1991-10-01), None
patent: 19715 244 (1998-10-01), None
patent: 0 428 389 (1991-05-01), None
patent: 0 476 300 (1992-03-01), None
patent: 08266859 (1996-10-01), None
patent: WO 86/02918 (1986-05-01), None
patent: WO 02/09852 (2002-02-01), None
patent: WO 02/28513 (2002-04-01), None
De Bruijn, et al, “Thermal Decomposition of Aqueous Manganese Nitrate Solutions”, Thermal Analysis, ICTA, Berkhaeuser, Verlag, Basel, Boston, Stuttgart, 1980: 393-398.
Elvers, Barbara, “Manganese,” Ullmans Encyclopedia of Industrial Chemistry, Basel, Switzerland? Ed., No Date.
Il'chenko, Kucha, Chernomordik, Andreeva, Ivabova, “Path and Products of Thermal Decomposition of Mn(NO3)2 in Aqueous Nitric Acid Solutions,” Plenum Publishing Corp., 1985, Northwest Correspondence Polytechnic Institute, Zhurnal Prikladnoi Khimii, vol. 58, May 21, 1984: pp. 984-989.
Karlsson and Rosenberg, “Flue Gas Denitrification. Selective Catalytic Oxidation of NO and NO2 Am. Chem. Soc.”, published in Ind. Chem. Process Des. Dev., 1984: No. 23, pp. 808-814.
Stiles, et al., “Selective Catalytic Reduction of NOx in the Presence of Oxygen,” Ind. Chem. Res., 1994: 33, pp. 2259-2264.
Uno, et. al., “A New Dry Process of SO2 Removal From Flue Gas Proceedings,” 7th world petroleum congress, vol. 9, pp. 289-295, Elsivier publishing Co, 1967.
Vadjic, et. al., “The Effect of MnO2 and Some Mn Salts on the Behaviour of SO2 in the Air,” The Science of the Total Environment, 44 (Feb. 18, 1985) 245-251, Elsevier Publishers.
Kanungo, Parida and Sant, “Studies on MnO2—II: Relationship Between Physico . . . Activity . . . Synthetic Mn” Electrochemiica Acta, 26 (8), pp. 1147-1156, 1981? Dec. 15, 1980.
Lawn, et. al., “The Effects of High-Energy Milling on the Catalytic Behaviour of MnO2,” Power Technology, 20 (1978) 207-210, Elsevier Sequoia, S.A.
Strobel and Charenton,

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