Pretreating oil shale with organic acid to increase retorting yi

Mineral oils: processes and products – By treatment of solid mineral – e.g. – coal liquefaction – etc.

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208403, 208415, 208428, 208435, C10G 100

Patent

active

052777960

ABSTRACT:
A process for pretreating oil shale prior to retorting by contacting with an organic acid, such as formic and acetic acids, at temperatures below about 100.degree. C. for a period of time sufficient to react at least a portion of the oil shale carbonates and separating the shale from the organic acid solution containing at least a major portion of the reaction products of the carbonates and organic acid. The process is preferably carried out in an aqueous solution of organic acid having a pH of 3 and less for a time of about 1/2 to about 4 hours and at ambient temperatures about 20.degree. to about 30.degree. C. Pretreatment of oil shale by this process prior to retorting results in higher liquid and aromatic product fractions being produced by conventional retorting.

REFERENCES:
patent: 1605761 (1926-11-01), Nielsen
patent: 4209385 (1980-06-01), Stover
patent: 4587005 (1986-05-01), Siskin et al.
patent: 4668380 (1987-05-01), Wolff et al.
patent: 5091076 (1992-02-01), So et al.

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