Pressure induced swelling in microporous materials

Drug – bio-affecting and body treating compositions – Radionuclide or intended radionuclide containing; adjuvant... – Coated – impregnated – or colloidal particulate

Reexamination Certificate

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C424S001110, C424S450000, C424S489000

Reexamination Certificate

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07074386

ABSTRACT:
A method for capturing specified materials which includes contacting a microporous material with a hydrostatic fluid having at least one specified material carried therein, under pressure which structurally distorts the lattice sufficiently to permit entry of the at least one specified material. The microporous material is capable of undergoing a temporary structural distortion which alters resting lattice dimensions under increased ambient pressure and at least partially returning to rest lattice dimensions when returned to ambient pressure. The pressure of the fluid is then reduced to permit return to at least partial resting lattice dimension while the at least one specified material is therein. By this method, at least one specified material is captured in the microporous material to form a modified microporous material.

REFERENCES:
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patent: 2004/0115269 (2004-06-01), Vogt et al.
Lee et al, “First Structural Investigation of a Super-Hydrated Zeolite”, J. Am. Chem. Soc., 2001, 123, pp. 12732-12733.
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Lee et al., “Phase Transition of Zeolite RHO at High-Pressure,”J. Am. Chem. Soc., vol. 123, pp. 8418-8419, (Published on Web Aug. 3, 2001).
Lee et al., “First Structural Investigation of a Super-Hydrated Zeolite,”J. Am. Chem. Soc., vol. 123, pp. 12732-12733, (Published on Web Nov. 22, 2001).
Lee et al., “Pressure-Induced Volume Expansion of Zeolites in the Natrolite Family,”J. Am. Chem. Soc., vol. 124, pp. 5466-5475, (Published on Web Apr. 18, 2002).
Moroz et al., “Pressure-Enhanced Molecular Self-Diffusion in Microporous Solids,”Microporous and Mesoporous Materials, vol. 42, pp. 113-119 (2001).
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