Catalyst – solid sorbent – or support therefor: product or process – Irradiation by – or application of – electrical – magnetic or...
Patent
1998-11-20
2000-05-09
Wu, David W.
Catalyst, solid sorbent, or support therefor: product or process
Irradiation by, or application of, electrical, magnetic or...
502108, 502117, 502152, 526132, 526160, 526943, 526904, 526351, 526352, B01J 3734
Patent
active
060604166
ABSTRACT:
A high-performance prepolymerized solid catalyst is prepared by polymerizing an olefin onto an olefin polymerization catalyst in a heterogeneous system under irradiation with an elastic wave, wherein the olefin is prepolymerized in an amount of not less than 0.1 g based on 1 mmol of a transition metal contained in the olefin polymerization catalyst. The elastic wave is preferably an ultrasonic wave. In a process for heterogeneous polymerization of an olefin, an olefin is subjected to slurry polymerization or gas phase polymerization in the presence of the prepolymerized solid catalyst. In a process for heterogeneous polymerization of an olefin, an olefin may be polymerized onto the olefin polymerization catalyst in a heterogeneous system under irradiation with an elastic wave to prepare polyolefin. Therefore, the heterogeneous polymerization of an olefin can be stably conducted and polyolefins of uniform property and high quality can be obtained.
REFERENCES:
patent: 5719095 (1998-02-01), Brekner et al.
Abstract of Japanese Laid Open Application Publication No. 62-297302 (Dec. 24, 1987), Patent Abstracts of Japan, vol. 12, No. 191 (C-501) (1988).
Kobata Atsuo
Matsumoto Tetsuhiro
Choi Ling-Siu
Mitsui Chemicals
Wu David W.
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