Preparation process of tert-butylphenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568780, 568783, 568784, C07C 3716

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active

053997867

ABSTRACT:
The present invention has as purpose a process for the manufacture of tert-butylphenols, mainly of tertbutyl-4-phenols from a phenol and an alkyltert-butylether. The improvement consists in separating in at least two steps, the reaction of phenol alkylation and transalkylation/isomerization of undesirable alkyltert-butylphenols, enabling the flexibilization of the type and quality of end product, and easily adapt to the demands of the market, plus the fact that the total yield improved as well as this improvement has good industrial hygiene properties.
Tert-butylphenols are useful intermediate products is the manufacture of phenolic resins or antioxydizing agents for rubber and for several plastic substances.

REFERENCES:
patent: 4359591 (1982-11-01), Fremery et al.
patent: 4370506 (1983-01-01), Ancillotti et al.
Chemical Abstracts, vol. 96, No. 17, 26 Apr. 1982, Columbus, Ohio, US; abstract No. 142445, *abrege* & BR-A-8 002 607 (Rhodia S.A.).

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