Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1985-12-02
1987-04-07
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
562406, C07C 6976, C07C 5114
Patent
active
046563067
ABSTRACT:
Disclosed herein is a process for preparing a corresponding cinnamate ester by the reaction of a styrene compound, carbon monoxide, an alcohol and oxygen by using a main catalyst composed of (a) a platinum group metal or a compound thereof and (b) a copper or iron compound and in the presence of a promoter, wherein the concentration of the metal of the component (a) is controlled at 5.5.times.10.sup.-4 gram atom/liter or below in the liquid reaction mixture and further the ratio of the component (b) to the metal of the component (a) is maintained at 50 moles/gram atom or above so as to carry out the reaction.
REFERENCES:
patent: 3530168 (1970-09-01), Biale
Matsuhisa Toshio
Sudo Isamu
Takaki Usaji
Killos Paul J.
Mitsui Toatsu Chemicals Incorporated
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