Preparation process of 4,4'-biphenol, precursor of same and prep

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568717, 568719, 568721, 568722, 568723, C07C 3914, C07C 3700

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049393065

ABSTRACT:
A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.
4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

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patent: 4877907 (1989-10-01), Miura et al.
Chem. & Ind., 1437 (1958).
J. Am. Chem. Soc., 76, 1733 (1954).

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