Preparation of zerovalent phosphine substituted rhodium compound

Details Preparation of zerovalent phosphine substituted rhodium compound Preparation of zerovalent phosphine substituted rhodium compound

1974-02-06

1976-03-23

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260598, 260601H, 260602, 260486R, 260526R, 2604651, 260449R, 260551R, 260615R, C07C 4508

Patent

active

039460827

ABSTRACT:
A process for preparing oxygenated products comprising aldehydes, which have high normal to branched-chain isomer ratios. The process involves using particularly characterized rhodium-containing complex catalysts under a specific combination of carefully controlled reaction conditions. The product aldehydes as made above may be condensed and hydrogenated to form saturated aldehyde dimers thereof.

REFERENCES:
Cotton et al., Advanced Inorganic Chem., 2nd Edit., p. 1010, 1966.
Chaston et al., Chemical Communications, p. 964, 1967.

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