Preparation of zerovalent nickel complexes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 1504

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044168250

ABSTRACT:
An improved, continuous process for the preparation of hydrocyanation catalysts comprising zerovalent nickel complexes with organophosphorus compounds (ligands) by controlling the temperature of the reaction relative to the amount of ligand and conducting the reaction in the presence of a chlorine ion and organic nitrile such as adiponitrile.

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patent: 3903120 (1975-09-01), Shook, Jr. et al.
patent: 4055582 (1977-10-01), Fahey

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