Preparation of vesiculated core/shell polymeric particles

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

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428407, 428515, 428523, 521 57, 521 60, 521 62, 521 63, 525201, 525902, B32B 516

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052292096

ABSTRACT:
A process for the manufacture of core/shell polymer particles comprises forming a core particle containing acid functionality, a first shell around said core of a copolymer of a nonionic monoethylenically unsaturated aromatic monomer and a copolymerisable polar monomer in an amount of at least 15% by weight of the copolymer and having a solubility in water at 20.degree. C. of at least 1% by weight and a second shell around said first shell of a polymer or copolymer of a nonionic monomer having a solubility in water at 20.degree. C. of less than 1% by weight and swelling the particle with a non-volatile alkali to generate one or more vesicles.
Preferably each shell contains a polymer or copolymer of styrene.

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