Preparation of vanadium III oxidic compounds and dehydrogenation

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By dehydrogenation

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585629, 585630, 585663, C07C 5333

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047629614

ABSTRACT:
The vapor phase dehydrogenation of hydrocarbons is achieved with a spinel of the formula AV.sub.2-x C.sub.x O.sub.4 where A is a bivalent metal, V is vanadium substantially in +3 oxidation state, C is a trivalent metal, or with a crystalline perovskite DV.sub.1-y C.sub.y O.sub.3 where D is one or more of Y, the rare earths and Bi, and V is again vanadium in +3 oxidation state.

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