Preparation of unsaturated ethers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260611R, 260613D, 260613R, C07C 4106, C07C 4110

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active

039707059

ABSTRACT:
Saturated and/or unsaturated monohydric alcohols are added to allylic halides in the presence of copper (I) halide and a solid organic-insoluble acid acceptor such as MgO to form ethers in which at least one and preferably both of the organic groups attached to the ether oxygen atom contains a single carbon-to-carbon double bond.

REFERENCES:
patent: 1941108 (1933-12-01), Reppe
patent: 2042219 (1936-05-01), Groll et al.
patent: 2176055 (1939-10-01), Britton et al.
patent: 2382031 (1945-08-01), Soday
patent: 2560350 (1951-07-01), Jelinek
patent: 3271461 (1966-09-01), Stephenson
patent: 3487114 (1969-12-01), Irick et al.

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