Preparation of unsaturated epoxy ester resin and carboxylated un

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528112, 528115, 525 20, 525 36, 525531, 525533, 525922, C08G 6510

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053190602

ABSTRACT:
A method of preparing an unsaturated ester resin having improved storage stability is disclosed. An epoxy compound and polymerizable unsaturated monocarboxylic acid are reacted in the presence of a trivalent organic phosphorous catalyst. The catalyst is subsequently deactivated by oxidation. The resin may then be reacted with an acid anhydride.

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P. D. Bartnett, E. F. Fox, R. E. Davis: "Reactions of Elemental Sulfur. Cationic Effects in the Reaction of Sulfur Triphenylphosphine" J. Am. Chem. Soc. 83 pp. 103-109 (1961).
M. J. Boskin and P. B. Dinney, "Reactions of Episulfides and Epoxides with Trisubstituted Phosphines," Chemistry and Industry pp. 330-331 (1959).

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