Preparation of trimethylaluminum

Organic compounds -- part of the class 532-570 series – Organic compounds – Aluminum containing

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556170, C07F 506

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active

050157507

ABSTRACT:
Trimethylaluminum can be formed by reacting a methylaluminum chloride, such as dimethylaluminum chloride, with sodium in the presence of an effective amount of an alkali or alkaline earth metal fluoride (e.g., sodium fluoride) to enhance the reaction.

REFERENCES:
patent: 2786860 (1957-03-01), Ziegler et al.
patent: 2839556 (1958-06-01), Ziegler et al.
patent: 2863894 (1958-12-01), Smith
patent: 2909547 (1959-10-01), Ziegler et al.
patent: 3006942 (1961-10-01), Nobis
Lyle F. Albright, "The Properties, Chemistry and Synthesis of Alkyl Aluminums," Chemical Engineering, Dec. 4, 1967, pp. 179-186.

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