Preparation of TiCl.sub.3 coordination complexes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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556 51, C07F 1700, C07F 300

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053670850

ABSTRACT:
TiCl.sub.3 coordination complexes with ethers are prepared by adding TiCl.sub.3.1/3AlCl.sub.3 to an ether solvent so as to form a solid TiCl.sub.3 -ether coordination complex in said solvent.

REFERENCES:
Inorganic Syntheses, vol. 21, 1982, pp. 137-138, Tetrahydrofuran Complexes of Selected Early Transition Metals.
J. Org. Chem. 1989, 54, pp. 3748-3749, An Optimized Procedure for Titanium-Induced Carbonyl Coupling, J. E. McMurry, et al.

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