Preparation of thin ceramic films via an aqueous solution route

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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427 62, 427 63, 427226, 427168, B05D 302, B05D 506, B05D 512, C23C 1802

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048807729

ABSTRACT:
A new chemical method of forming thin ceramic films has been developed. An aqueous solution of metal nitrates or other soluble metal salts and a low molecular weight amino acid is coated onto a substrate and pyrolyzed. The amino acid serves to prevent precipitation of individual solution components, forming a very viscous, glass-like material as excess water is evaporated. Using metal nitrates and glycine, the method has been demonstrated for zirconia with various levels of yttria stabilization, for lanthanum-strontium chromites, and for yttrium-barium-copper oxide superconductors on various substrates.

REFERENCES:
patent: 2763569 (1956-09-01), Bradstreet et al.
Kawai et al "Formation of Y-B.sub.a -C.sub.u -O Superconducting Film by a Spray Pyrolysis Method", Jpn. J. Appl. Phys. vol, 26(10) Oct. 1987 L1740-L1742.

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