Preparation of tetraketones

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260297R, C07C 4976

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active

040828069

ABSTRACT:
A method of preparing tetraketone precursors which are useful in the production of high temperature resistant polyquinoxaline resins. Suitable diketones are oxidized with a halogenating agent, such as cupric halide or hydrogen bromide, and dimethylsulfoxide to produce the corresponding tetraketone. The tetraketones which can be produced by the instant process have the formula: ##STR1## wherein R is hydrogen or an aryl, substituted aryl, heterocyclic or substituted heterocyclic radical and R' is an aryl, substituted aryl, arylalkyl, arylether, arylthioether, arylsulfoxide, arylsulfone, heterocyclic or substituted heterocyclic radical.

REFERENCES:
patent: 3839497 (1974-08-01), Wentworth
Fieser et al., Reagents for Organic Synthesis, pp. 161-162, 303-304.

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