Preparation of siloxy-bridged metallocenes

Details Preparation of siloxy-bridged metallocenes Preparation of siloxy-bridged metallocenes

2008-06-12

2009-06-09

Gonzalez, Porfirio Nazario (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

C556S012000, C556S457000

Reexamination Certificate

active

07544825

ABSTRACT:
A method for making siloxy-bridged ligand precursors and metallocene complexes is disclosed. Indanone enolates react with cyclopentadienylsilyl compounds to produce ligand precursors, which are reacted with a Group 3-10 transition metal source to generate metallocene complexes. The method provides simple, regioselective access to particular siloxy-bridged metallocenes starting from easily elaborated indanones.

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