Preparation of silicon and germanium hydrides containing two dif

Details Preparation of silicon and germanium hydrides containing two dif Preparation of silicon and germanium hydrides containing two dif

1986-02-18

1988-10-11

Doll, John

Chemistry of inorganic compounds

Treating mixture to obtain metal containing compound

Group iva metal

423324, 423414, 423644, C01G 1700

Patent

active

047770236

ABSTRACT:
A method for preparing a hydride containing at least two different Group 4A atoms wherein at least one of the Group 4A atoms is silicon or germanium. The method includes the steps of reacting an alkali metal and a macrocyclic compound with a silicon or germanium hydride to form a salt. The salt is then reacted with a Group 4A halide. The resulting hydrides are useful as deposition feedstock material for use in the formation of hydrogenated amorphous silicon alloy in the fabrication of photovoltaic devices and other semiconductor devices.

REFERENCES:
patent: 4362884 (1982-12-01), Arkles
patent: 4374111 (1983-02-01), LeFrancois
patent: 4376190 (1983-03-01), Schultz et al.
patent: 4379766 (1983-04-01), Mack et al.
patent: 4423238 (1983-12-01), Fenton
patent: 4480009 (1984-10-01), Berger
patent: 4548917 (1985-10-01), Lepage et al.
Morrison et al., "Synthesis and Characterization of the (Halosilyl) Methyl-Silanes," Journal of Organometallic Chemistry (1975) vol. 92, pp. 163-168.
Ring et al., "Preparation and Reactions of Potasium Silyl," J. Am. Chem. Soc. (1960) vol. 83, pp. 802-805.
Varma et al., "A New Synthesis of Germylsilane," Angew. Chem. Internat. Edit. (1964) vol. 3, No. 8, p. 586.
Andrews et al., "Further Studies on the Silicon-Germanium Hydrides," J. Chem. Soc. (A) (1966) pp. 46-48.
Gokhale et al., "Synthesis of the Higher Silanes and Germanes," J. Inorg. Nucl. Chem. (1965) vol. 27, pp. 1911-1916.
Spanier et al., "Synthesis of Germylsilane from Silane and Germane in a Silent Electric Discharge," Inorg. Chem. (1963) vo. 2, pp. 215-216.
Timms et al., "The Silicon-Germanium Hydrides," J. Chem. Soc. (1964) pp. 1467-1475.
Phillips et al., "Some Applications of Gas Chromatography in Inorganic Chemistry," J. Anal. Chem. (Apr. 1963) vol. 35, No. 4, pp. 505-510.
Mackay et al., "Silicon-Germanium Hydrides," Si.sub.2 GeH.sub.8," J. Chem. Soc. (A) vol. 19, pp. 2937-2942 (1969).
Benkeser et al., "Sylation of Organic Halides. A New Method of Forming the Carbon-Silicon Bond," J. Am. Chem. Soc. vol. 91, No. 13, pp. 3666-3667 (1969).
Choo et al., "Silicon- and Germanium-Substitution in Silylgermane, H.sub.3 SiGeH.sub.3, " J. Chem. Research (S), 1981, 76, J. Chem. Research (M), 1981, 920-933.
Schenk et al., "Preparative Inorganic Chemistry, Brauer," pp. 664-665.
Bravo-Zhitvotovskii, et al., "Complexation of Triethylsilyllithium and its Analogs with Donor Ligands," Izv. Akad. Nauk. SSSR, Ser. Khim. No. 11, pp. 2560-2651 (1979).
Bullard et al., "Compounds of the Triphenyltin (II) Ion," Aust. Chem. (1981) vol. 34, pp. 1337-1340.
Power et al., "Mononuclear Lithium Amides using a Crown Ether: X-Ray Crystal Structure of Lithium Bis(Trimethylsilyl)Amide 12-Crown-4,[LiN(SiMe.sub.3).sub.2 12-Crown-4]," J. Chem. Soc., Chem. Commun., 1984 pp. 358-359.
Dye et al., "Solubilization of Alkali Metals in Tetrahydrofuran and Diethyl Ether by Use of a Cyclic Polyether," J. Am. Chem. Soc. vol. 92, No. 17, pp. 5226-5228 (1970).

Affiliated with

Also associated with

Rating

Preparation of silicon and germanium hydrides containing two dif does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Preparation of silicon and germanium hydrides containing two dif, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Preparation of silicon and germanium hydrides containing two dif will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1957375