Preparation of secondary thiols

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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C07C14906

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active

046380930

ABSTRACT:
A process is disclosed for the preparation of secondary thiols by the addition of H.sub.2 S to C.sub.10 to C.sub.30 linear olefins in the presence of certain zeolite catalysts. The process achieves high selectivity to the secondary thiol and minimizes formation of dialkyl sulfide by-products. The secondary thiol products are of particular advantage for use as intermediates in the preparation of surfactant chemicals.

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