Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-10-23
1976-05-11
Sneed, Helen M. S.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260583R, C07C 8510
Patent
active
039563898
ABSTRACT:
A process for producing secondary alkyl primary amines having from 10 to 50 or, from about 10 to about 13, or from about 14 to 50 carbon atoms from crude n-paraffin oximes derived by the photonitrosation of C.sub.10 to C.sub.50 or C.sub.10 to C.sub.13 or C.sub.14 to C.sub.50 n-paraffins, said process comprising hydrogenation in a polar solvent in the presence of ammonia and a metal catalyst. The crude n-paraffin oximes are contaminated with ketones and nitroso halides. By the process of this invention, these impurities are likewise converted into the corresponding secondary alkyl primary amines.
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Wagner et al., Synthetic Organic Chemistry, John Wiley & Sons, Inc., N.Y., pp. 654-663 (1953).
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Edwards Robert Sammie
Kuntschik Lawrence Frank
Rigdon Orville Wayne
Darsa George J.
Ries C. G.
Sneed Helen M. S.
Texaco Inc.
Whaley T. H.
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