Preparation of radiation-curable acrylates that are storage stab

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522 25, 522 28, 522 30, 522 64, 522 65, C08F 246

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active

056021917

ABSTRACT:
Radiation-curable acrylates are prepared by a process in which the hydroxy compound is reacted with acrylic acid or methacrylic acid in a first stage and, in a second stage, the reaction product of the first stage is reacted with an epoxide compound in the presence of, as a catalyst, a quaternary ammonium or phosphonium compound of the general formula ##STR1## where X.sup.- is an opposite ion and R.sup.1 to R.sup.4 independently of one another are each C.sub.1 -C.sub.18 -alkyl which may be substituted by one or two phenyl groups or are each C.sub.6 -C.sub.12 -aryl which may be substituted by one or two C.sub.1 -C.sub.6 -alkyl groups.

REFERENCES:
patent: 3432478 (1969-03-01), May
patent: 3833384 (1974-09-01), Noonan et al.
patent: 4205018 (1980-05-01), Nagasawa et al.
patent: 5096938 (1992-03-01), Beck et al.

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