Preparation of polyolefin incorporating functional groups from m

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5261692, 5261693, 526240, 526241, 5253261, 5253266, 5253282, 5253285, 5253295, 525340, 525344, 525355, 525374, 525383, C08F23004, C08F 812

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051532824

ABSTRACT:
Polymers of olefin monomers and a substantially uniform concentration of carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers. Polymers of olefin monomers and carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers substantially devoid of halogen. Method for preparing polymers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds to form masked, functional group-containing monomers and polymerizing polymer chain monomers with the masked, functional group-containing monomers to produce a polymer chain. Method for forming masked, functional group-containing monomers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds. Masked, carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers.

REFERENCES:
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patent: 3492277 (1970-01-01), Clark
Organic Chemistry, Morrison and Boyd (4th ed.) Allyn and Bacon, Inc., Boston, 436-446 (1983).
Lindsay, Block Copolymerization of Ethylene, Propylene and Acrylic Acid Esters, Block Copolymers Science and Tech., Dale Meier (ed.), Harwood Academic, N.Y., 53-62 (1979).
Matsumura et al., Copolymerization of Propylene With Acrylate By Ziegler-Natta Type Catalyst, J. Polym. Sci., 9, 471-483 (1971).

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