Preparation of polycarbynes and diamond-like carbon materials ma

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From halogenated hydrocarbon reactant

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585 17, 585 19, 585 20, 585 23, 585352, C07C 1328, C08G 6100

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055168841

ABSTRACT:
Synthesis and characterization of polycarbynes, a new class of carbon-based random network polymers. The network backbones of the polymers are composed of tetrahedrally hybridized carbon atoms, each bearing one substituent and linked via three carbon-carbon single bonds into a three-dimensional continuous random network backbone. Silicon, germanium, tin, lead, Group 13 through Group 16 elements, lanthanides, and Group 4 metals can be incorporated into the polymer backbone. The atomic-level carbon network backbone confers unusual properties on the polymers, including thermal decomposition to form diamond or diamond-like carbon.

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