Preparation of polyaryl ethers with nitrogen compound catalysts

Details Preparation of polyaryl ethers with nitrogen compound catalysts Preparation of polyaryl ethers with nitrogen compound catalysts

1992-08-20

1994-03-29

Anderson, Harold D.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

From phenol, phenol ether, or inorganic phenolate

528125, 528128, 528171, 528174, 528219, C08G 6540

Patent

active

052985920

ABSTRACT:
A process for preparing polyaryl ethers of the formula I or Ia ##STR1## by condensation of at least one appropriate bisphenol with at least one appropriate aromatic dichloride in the presence of an alkali metal carbonate in a dipolar aprotic solvent, is carried out in the presence of a catalyst selected from the alkali metal nitrites and the group of compounds of the formula II ##STR2## where r.sup.1 and r.sup.3 are each hydrogen, C.sub.7 -C.sub.16 -phenylalkyl, C.sub.1 -C.sub.12 -alkoxy, fluorine, chlorine, bromine, iodine or nitro, and R.sup.2 is nitro or nitroso, or ##STR3## where R.sup.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, fluorine, chlorine, bromine or iodine.

REFERENCES:
patent: 4105636 (1978-08-01), Taylor

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