Preparation of polyamides by anionic polymerization with substit

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 78P, C08G 6918

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active

040425720

ABSTRACT:
Preparation of polyamides by anionic polymerization or copolymerization of cyclic lactams which comprises conducting the polymerization in the presence of a six membered cyclic co-catalyst containing three ##STR1## groups and represented by the formula: ##STR2## wherein R.sub.1 and R.sub.2 are each selected from the group consisting of aryl groups, or containing two ##STR3## groups and represented by the formula: ##STR4## wherein R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each selected from the group consisting of alkyl (C 1-18) and aryl groups and combinations thereof, and X.sub.1, X.sub.2 and X.sub.3 are either sulphur or oxygen, except that at least two members of the group X.sub.1, X.sub.2 and X.sub.3 must be oxygen.
Preferably, the aryl contains from 1 to 3 benzene rings, or can be an alkoxyaryl or dialkylaminoaryl. The alkyl can be an arylated alkyl.

REFERENCES:
patent: 3017391 (1962-01-01), Mottus et al.
patent: 3448085 (1969-06-01), Pietrusza et al.
patent: 3803101 (1974-04-01), Matsuo et al.

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