Preparation of poloxy-alkylene glycols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568606, 568607, 568616, 560103, 560240, C07C 4101, C07C 4102

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054162408

ABSTRACT:
Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.

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