Preparation of perfluorinated organic sulfonyl fluorides

Chemistry: electrical and wave energy – Processes and products

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260503, B01K 100, C07C14370, C25B 308

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active

039517624

ABSTRACT:
In the electrochemical fluorination of an alkanesulfonyl halide wherein an electric current is passed through a cell containing said alkanesulfonyl halide dissolved in hydrofluoric acid to produce a perfluorinated alkanesulfonyl fluoride, the improvement which comprises including in said cell an unsaturated cyclic sulfone.

REFERENCES:
patent: 2732398 (1956-01-01), Brice et al.
patent: 3423299 (1969-01-01), Loree
patent: 3623963 (1971-11-01), Voss et al.

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