Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing
Patent
1986-05-19
1988-12-20
Ceperley, Mary E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Sulfur containing
568 47, 568 48, 568 49, 568 50, 568 52, 568 53, 568 54, C07C14802
Patent
active
047926333
ABSTRACT:
Strong acids, e.g., aluminosilicates and sulfonic acids are employed as catalysts for the (alkyl or aryl)thiolation of phenols using dialkyl or diaryl disulfides and/or (alkyl- or arylthio)phenols as thiolating agents, and for the isomerization of (alkyl- or arylthio)phenols, to prepare ortho(alkyl- or arylthio)phenols as the predominant products.
REFERENCES:
patent: 2923743 (1960-02-01), Deffs et al.
patent: 3134818 (1964-05-01), Farah et al.
patent: 4324920 (1982-04-01), McKinnie et al.
patent: 4547593 (1985-10-01), Ranken
patent: 4599451 (1986-07-01), Wojtkowski
P. Ranken et al., Synthesis, Feb. 1984, pp. 117-119, Alkylthiolation of Phenols.
B. Farah et al., J. Organic Chemistry, vol. 28, pp. 2807-2809 (1963), Alkylmercaptophenols by Sulfenylation of Phenols.
Ceperley Mary E.
E. I. Du Pont de Nemours and Company
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