Preparation of organophosphorus compounds

Details Preparation of organophosphorus compounds Preparation of organophosphorus compounds

1988-07-08

1990-05-01

Doll, John

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus containing

568 8, C07F 953

Patent

active

049220250

ABSTRACT:
Organophosphorus compounds are prepared by reacting an unsaturated compound, such as a striaght-chain, branched or cyclic olefin or a diene having conjugated or nonconjugated double bonds, with a phosphine by a process in which phosphine and/or phosphine-containing compounds are subjected to an addition reaction with the unsaturated compounds in the presence of a solid heterogeneous catalyst. Particularly suitable heterogeneous catalysts are zeolites and phosphates.

REFERENCES:
patent: 2957931 (1960-10-01), Hamilton et al.
patent: 3855311 (1974-12-01), Staendeke
patent: 3954859 (1976-05-01), Jurewicz et al.
patent: 4073810 (1978-02-01), Hestermann et al.
patent: 4717785 (1988-01-01), Paxson
J. Chem. Soc. 1083 (1963).
General Chemistry, 5th Edition, William H. Nebergall et al., D.C. Heath and Company, Lexington, MA, Toronto London.

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