Preparation of organometallic and organobimetallic compounds

Compositions – Compositions containing a single chemical reactant or plural... – Inorganic reactant other than sulfur containing

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25218212, C09K 300

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active

051416670

ABSTRACT:
A process for producing organometallic compositions by reacting an organohalide with a mixture of two metals; one being an alkali metal, the other being selected from magnesium, calcium, barium and zinc in a hydrocarbon solvent containing 0.5 to 2.0 moles of a Lewis Base per mole of organohalide.

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patent: 4342708 (1982-08-01), Sakurai et al.
patent: 4429054 (1984-01-01), Morrison
Lithium-7 and Proton Nuclear Magnetic Resonance Spectra of Methyllithium/Dimethylmagnesium (Zinc, Cadmium) in Tetrahydrofuran and Methyllithium/Dimethylcadmium in Ether; L. M. Seitz & B. F. Little, J. Organometal. Chem., 18 (1969) 227-241.
Wakefield, "The Chemistry of Organolithium Compounds", pp. 198-199, Pergamon Press.

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