Preparation of nitro compounds by vapor phase nitration of organ

Details Preparation of nitro compounds by vapor phase nitration of organ Preparation of nitro compounds by vapor phase nitration of organ

1983-12-19

1985-05-14

Sebastian, Leland A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568947, C07C 7902

Patent

active

045173923

ABSTRACT:
A process for selectively forming nitro compounds by contacting, at elevated temperature and pressure and in a homogeneous gas phase, an alcohol having from two to ten carbon atoms with nitrogen dioxide alone or in the presence of oxygen and/or water.

REFERENCES:
patent: 2894041 (1959-07-01), Berg
patent: 3689576 (1972-09-01), Bachman et al.
patent: 3780115 (1973-12-01), Lhonore et al.
patent: 3869253 (1975-03-01), Lhonore et al.
patent: 4260838 (1981-04-01), Lhonore et al.
patent: 4313010 (1982-01-01), Lhonore et al.
Nitration Studies, Bachman et al., 35, J. Org. Chem. 4229 (1970).
Vapor Phase Nitration of Aliphatic Ethers, Alcohols, Ketones and Carboxylic Acids, Hass et al., 76, JACS 2692, (1954).
Nitration of Gaseous Paraffins, Hass et al., 28, Ind. & Eng. Chem. 339.

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