Preparation of nitro compounds by vapor phase nitration of carbo

Details Preparation of nitro compounds by vapor phase nitration of carbo Preparation of nitro compounds by vapor phase nitration of carbo

1983-12-19

1985-05-14

Sebastian, Leland A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568927, 568947, C07C 7902

Patent

active

045173940

ABSTRACT:
A process for selectively forming nitroalkanes and nitroaromatics by contacting, at elevated temperature and pressure and in a homogeneous gas phase, an organic carboxylic acid having from two to ten carbon atoms with NO.sub.2 alone or in the presence of oxygen and/or water.

REFERENCES:
patent: 2894041 (1959-07-01), Berg
patent: 3689576 (1972-09-01), Bachman et al.
patent: 3780115 (1973-12-01), Lhonore et al.
patent: 3869253 (1975-03-01), Lhonore et al.
patent: 4260838 (1981-04-01), Lhonore et al.
patent: 4313010 (1982-01-01), Lhonore et al.
Nitration Studies, Bachman et al., 35 J. Org. Chem. 4229 (1970).
Vapor Phase Nitration of Aliphatic Ethers, Alcohols, Ketones and Carboxylic Acids, Hass et al., 76 JACS 2692 (1954).
Nitration of Gaseous Paraffins, Hass et al., 28 Ind. & Eng. Chem. 339.

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