Preparation of nitriles

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260465F, 260465K, C07C12170

Patent

active

041327284

ABSTRACT:
.alpha.,.beta.-Unsaturated nitriles are prepared from carbonyl compounds and then reduced by reaction with an alkanol and magnesium in the presence of an ammonium salt.

REFERENCES:
patent: 2307700 (1943-01-01), Moore
patent: 2745866 (1956-05-01), Rorig
Vigier et al., Bull. Soc. Chim., pp. 677-681 (1963).
Hitchings et al., J. Chem. Soc., pp. 1019-1028 (1956).
Jarrousse, Compt. rend., 244, pp. 2515-2518 (1957).

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