Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1978-11-02
1981-12-08
Doll, John
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
564397, 564398, C07C 8508
Patent
active
043049397
ABSTRACT:
The desired compounds, namely, N-phenyl-N'-alkylphenylenediamines, are prepared by the reductive alkylation of a nitrogen-containing diphenylamine and a ketone in the presence of hydrogen and a hydrogenation catalyst. The desired product may be obtained in a more economical way when effecting the process in a continuous manner by utilizing an organic solvent for the reaction which comprises an ether compound such as a monoether of a dihydric alcohol, a diether of a dihydric alcohol, or a cyclic diether.
REFERENCES:
patent: 2809994 (1957-10-01), Hinckley
patent: 4140718 (1979-02-01), Symon
patent: 4155936 (1979-05-01), Sturm
Morrison et al., "Organic Chemistry", 2nd Edition, p. 492 (1966).
Doll John
Hoatson Jr. James R.
Nelson Raymond H.
Page II William H.
UOP Inc.
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