Preparation of methyl mercaptan from carbon oxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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502216, 502219, 502220, 502222, 568 69, C07C14800

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active

044490062

ABSTRACT:
A process is provided for the manufacture of methyl mercaptan with substantial reduction of by-product methane by intimate mixture of carbon oxide, sulfur or hydrogen sulfide and hydrogen at elevated temperature and pressure with a single-phase, solid catalyst system comprising a porous alumina-containing support upon which is deposited a mixture of manganese sulfide and alkali metal sulfide.

REFERENCES:
patent: 3070632 (1962-12-01), Olin et al.
N. Shalunenko et al., Chem. Abstracts 85:165470w, (1976).

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