Preparation of metallocenes in one reaction step

Organic compounds -- part of the class 532-570 series – Organic compounds – Rare earth containing

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556 43, 556 46, 556 53, 556 58, 556136, 556144, C07F 500, C07F 1700, C07F 700, C07F 1100

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056418710

ABSTRACT:
Metallocenes are prepared by a process in which a metal salt is reacted with at least one alkali metal and with an unsaturated, cyclic hydrocarbon in the presence of a solvent in one reaction step.

REFERENCES:
patent: 2834796 (1958-05-01), Barusch et al.
patent: 2870183 (1959-01-01), Brantley
Chem. Abst., vol. 91, No. 21, Nov. 19, 1979, abst. No. 175478t, Handlir et al., "A simple synthetic method for chromocene and vanadocene", p. 678.

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