Preparation of metal chalcogenides from reactions of metal...

Chemistry of inorganic compounds – Selenium or tellurium or compound thereof

Reexamination Certificate

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C423S509000, C423S511000, C423S518000, C423S561100, C423S565000, C423S566100, C423S592100, C977S762000, C977S773000, C977S775000, C977S777000

Reexamination Certificate

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07393516

ABSTRACT:
A method of preparing metal chalcogenides from elemental metal or metal compounds has the following steps: providing at least one elemental metal or metal compound; providing at least one element from periodic table groups 13-15; providing at least one chalcogen; and combining and heating the chalcogen, the group 13-15 element and the metal at sufficient time and temperature to form a metal chalcogenide. A method of functionalizing the surface of semiconducting nanoparticles has the following steps: providing at least one metad compound; providing one chalcogenide having a cation selected from the group 13-15 (B, Al, Ga, In, Si, Ge, Sn, Pb, P, As, Sb and Bi); dissolving the chalcogenide in a first solution; dissolving the metal compound in a second solution; providing and dissolving a functional capping agent in at least one of the solutions of the metal compounds and chalcogenide; combining all solutions; and maintaining the combined solution at a proper temperature for an appropriate time.

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The English abstract of CN 1251348 A published on Apr. 26, 2000.
Feldman, Y. et al. “Bulk Synthesis of Inorganic Fullerine-like MS2 (M=Mo, W) from the Respective Trioxides and the Reaction Mechanism” Journal of the American Chemical Society, vol. 118, No. 23 (1996), pp. 5362-5367.

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