Preparation of macrocyclic polyetherimide oligomers from bis(tri

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528 21, 528 26, 528 34, 528126, 528128, 528170, 528171, 528172, 528173, 528174, 528175, 528179, 528185, 528188, 528220, 528229, 528353, 524600, C08G 802, C08G 7310, C08G 6926

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053628373

ABSTRACT:
Macrocyclic polyetherimide oligomer compositions are prepared by a displacement reaction at a temperature in the range of about 200.degree.-225.degree. C. between at least one fluorinated aromatic phthalimide and at least one phenolic trialkylsilyl ether compound. Preferably, a bis-fluoroimide and a bis-trialkylsilyl ether of a dihydroxyaromatic compound such as resorcinol are employed. The reaction is conducted by maintaining reagents A and B in high dilution in a dipolar aprotic organic liquid such as N-methylpyrrolidone, and in the presence of a catalytic amount of at least one substantially soluble fluoride. Preferably, a mixture of reagents A and B is added to solvent containing the catalyst.

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patent: 5229482 (1993-07-01), Brunelle
Bryant et al., "A-B Polyetherimides", Abstracts of the Fourth International Conference on Polyimides, pp. 69-71, Oct.30-Nov. 1, (1991).

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