Preparation of linear crystalline homopolybenzyl

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From halogenated hydrocarbon reactant

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528217, 528396, C08G 6102

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042594758

ABSTRACT:
Polybenzyls of high molecular weight and high crystallinity are obtained by polymerizing aralkyl halides in the presence of a catalyst comprising a complex of a Friedel-Crafts catalyst with a complexing agent which can be a nitroarene or a nitroalkane. The complex catalyst allows the polymerization to be run at higher temperatures and with higher rates. Yields are obtained up to 100%.

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