Preparation of insoluble polymer powders which are only slightly

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 71, C08F 234

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046476377

ABSTRACT:
Insoluble polymer powders which are only slightly swellable and are based on N-vinylpyrrolidone are prepared by polymerization of N-vinylpyrrolidone or a mixture of this with copolymerizable monomers and from 0.1 to 10% by weight, based on the total amount of monomers, of a crosslinking agent in a powder bed in the presence of a heat-transfer medium, which is inert to the reactants, and in the absence of oxygen and polymerization initiators, at from 90.degree. to 220.degree. C., while maintaining the powder state, circulating the reaction mass and evaporating the heat-transfer medium from the polymerization zone. The resulting insoluble polymers which are only slightly swellable are used as adsorbents or formulation assistants for fertilizers and crop protection agents.

REFERENCES:
patent: 3689439 (1972-09-01), Field
patent: 3933766 (1976-01-01), Hofmann
patent: 4013825 (1977-05-01), Denzinger et al.
patent: 4059552 (1977-11-01), Zweigle
patent: 4135043 (1979-01-01), Kast et al.
patent: 4361689 (1982-11-01), Patel
patent: 4451582 (1984-05-01), Denzinger

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