Preparation of hydrogen iodide, lithium iodide and methyl iodide

Chemistry of inorganic compounds – Halogen or compound thereof – Hydrogen halide

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Details

423499, 570101, C01B 713, C01D 312, C07C 1722

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active

043024327

ABSTRACT:
Disclosed is a process for the preparation of hydrogen iodide, lithium iodide and methyl iodide by the reaction under anhydrous conditions of hydrogen and iodine in a non-alcoholic solvent using a homogeneous rhodium catalyst. Lithium iodide and/or methyl iodide are obtained by including lithium acetate and/or methyl acetate in the reaction medium.

REFERENCES:
patent: 1890894 (1932-12-01), Weston
patent: 3049406 (1962-08-01), Grant et al.
patent: 3154382 (1964-10-01), Gerald
patent: 3761579 (1973-09-01), Curtis et al.
patent: 3784518 (1974-01-01), Paulik
patent: 3848065 (1974-11-01), Paulik

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